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Collisional quantum interference effect on rotational energy transfer in an atom-diatom system
Sun MT, Sha GH, Cong SL, Ma FC, Xie JC, Zhang CH
CHEMICAL PHYSICS LETTERS
339 (5-6): 413-420 MAY 15 2001
Document type: Article Language: English Cited References: 23 Times Cited: 2
Abstract:
The theoretical model of collisional quantum interference (CQI) in intramolecular rotational energy transfer is described in an atom-diatom system, based on the first Born approximation of time-dependent perturbation theory and considering a long-range interaction potential. The relation between differential and integral interference angles is obtained. For the CO A(1)Pi (v = 0)/e(3)Sigma (-)(v = 1)-He collision system, the calculated integral interference angles are consistent with the experimental values. The physical significance of interference angle and the essential factors it depends on as well as the influence of the short-range interaction on CQI are discussed. (C) 2001 Elsevier Science B.V. All rights reserved.
KeyWords Plus:
TRIPLET MIXED STATES, TIME-DOMAIN, MOLECULES, SPECTROSCOPY, TRANSITIONS, NA-2
Addresses:
Sun MT, Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
Dalian Univ Technol, Dept Phys, Dalian 116023, Peoples R China
Liaoning Univ, Dept Phys, Shenyang 110036, Peoples R China
Publisher:
ELSEVIER SCIENCE BV, AMSTERDAM
IDS Number:
434BP
ISSN:
0009-2614
Collisional quantum interference on rotational energy transfer: physical interpretation of the interference angle
Sun MT, Liu J, Ma FC, Sha GH
CHEMICAL PHYSICS
274 (2-3): 175-186 DEC 15 2001
Document type: Article Language: English Cited References: 28 Times Cited: 1
Abstract:
A dynamic model of collisional quantum interference (CQI) on rotational energy transfer in an atom-diatom system is presented, based on the first-order Born approximation of time-dependent perturbation theory and the long-range interaction potential. The interference angle, proposed by Sha, is described theoretically. The relation between the differential and the integral interference angle is shown. The key factors that the interference angle depends on are obtained. When the integral interference angle theta (TI)(S) = 90 degrees or 0 degrees, this model is the "gateway" model proposed by Gelbart and Freed or the 'complete coherence' model proposed by Alexander, respectively. If the quadrupole and dipole-quadrupole polarizibilities are not considered, i.e., Theta = 0 and beta = 0, this model is the model proposed by Sun, which has been used to simulate the CO (A(1)Pi -e(3)Sigma (-))-He experiment, and the calculated values are consistent with the experimental results. Moreover, this model can also be used to simulate molecular beam experiments to calculate differential cross-sections and differential interference angle. (C) 2001 Elsevier Science B.V. All rights reserved.
KeyWords Plus:
TRIPLET MIXED STATES, MOLECULES, CO, PERTURBATIONS, BAND
Addresses:
Sun MT, Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
Liaoning Univ, Dept Phys, Shenyang 110036, Peoples R China
Publisher:
ELSEVIER SCIENCE BV, AMSTERDAM
IDS Number:
507FE
ISSN:
0301-0104
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